Silver Trifluoromethanesulfonate

Catalogue number: S465100
Chemical name: Silver Trifluoromethanesulfonate
Synonyms: Trifluoro-methanesulfonic Acid Silver(1+) Salt; Silver (trifluoromethyl)sulfonate; Silver triflate; Silver trifluoromethanesulfonate; Silver trifluoromethanesulfonate; Silver Trifluoromethanesulphonate; Silver(1+) Triflate; Silver(1+) trifluoromethanesulfonate; Silver(I) Triflate; Silver(I) Trifluoromethanesulfonate; Trifluoromethanesulfonic Acid Silver(1+) Salt
CAS Number: 2923-28-6
Possible CAS #: 1493-13-6 free acid
Molecular form.: CAgF₃O₃S
Appearance: Light Grey Solid
Melting Point: >232°C (dec.)
Mol. Weight: 256.94
Storage: Hygroscopic, -20°C Freezer, Under inert atmosphere
Solubility: Methanol (Slightly), Water (Slightly)
Stability: No Data Available
Category: No Data Available
Boiling Point: No Data Available
Applications: Silver Trifluoromethanesulfonate is used to generate cationic rhodium catalysts from chlororhodium complexes for the hydrophosphination of acetylenes. It is also employed as a catalyst for the preparation of silyl ethers by hydrosilylation of aldehydes.
Dangerous Goods Info: NA
References: Hayashi, M., et al.: J. Org. Chem., 71, 9248 (2006); Xu, H., et al.: Org. Lett., 17, 66 (2015)
Peer Review Product Citations:

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