(αR)-α-[[(1,1-Dimethylethoxy)carbonyl]amino]-benzeneacetic Acid

Catalogue number: D469595
Chemical name: (αR)-α-[[(1,1-Dimethylethoxy)carbonyl]amino]-benzeneacetic Acid
Synonyms: (R)-α-[[(1,1-Dimethylethoxy)carbonyl]amino]-benzeneacetic acid; D-N-Carboxy-2-phenyl-glycine N-tert-butyl Ester; (2R)-2-(tert-Butoxycarbonylamino)-2-phenylethanoic Acid; (R)-2-((tert-Butoxycarbonyl)amino)-2-phenylacetic Acid; (R)-2-tert-Butoxycarbonylamino-2-phenylethanoic Acid; (R)-N-(tert-Butyloxycarbonyl)phenylglycine; (R)-N-Boc-2-amino-2-phenylacetic Acid; (R)-N-Boc-2-phenylglycine; (R)-[(tert-Butoxycarbonyl)amino]phenylethanoic Acid; BOC-D-Phg-OH; D-(-)-N-(tert-Butoxycarbonyl)phenylglycine; D-2-tert-Butoxycarboxamido-2-phenylacetic Acid; D-N-(tert-Butoxycarbonyl)-2-phenylglycine; N-(tert-Butoxycarbonyl)-D-2-phenylglycine; N-(tert-Butoxycarbonyl)-D-α-phenylglycine; N-(tert-Butoxycarbonyl)phenylglycine; N-Boc-D-phenylglycine; N-tert-Butoxycarbonyl-D-phenylglycine; N-tert-Butyloxycarbo
CAS Number: 33125-05-2
Possible CAS #: NA
Molecular form.: C₁₃H₁₇NO₄
Appearance: White Solid
Melting Point: 91-93°C
Mol. Weight: 251.28
Storage: Refrigerator
Solubility: DMSO, Methanol
Stability: No Data Available
Category: Amines, Aromatics, Catalyst
Boiling Point: No Data Available
Applications: (αR)-α-[[(1,1-Dimethylethoxy)carbonyl]amino]-benzeneacetic Acid is D-(+)-2-Phenylglycine (P327125) with Boc protecting group. (αR)-α-[[(1,1-Dimethylethoxy)carbonyl]amino]-benzeneacetic Acid is used as part of a catalyst combination to catalyze regioselective [4 + 2] cycloadditions of β-substituted cyclic enones and polyconjugated malononitriles. It can also be used to catalyze stereoselective preparation of polyfunctional nitrocyclohexene carboxaldehydes.
Dangerous Goods Info: NA
References:
Peer Review Product Citations:

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