[2,2’-Bis(diphenylphosphino)-1,1’-binaphthalene]chloro(p-cymene)ruthenium Chloride

Catalogue number: B430395
Chemical name: [2,2’-Bis(diphenylphosphino)-1,1’-binaphthalene]chloro(p-cymene)ruthenium Chloride
Synonyms: [1,1’-(1S)-[1,1’-Binaphthalene]-2,2’-diylbis[1,1-diphenylphosphine-κP]]chloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene]ruthenium(1+) Chloride; (S)-[[1,1’-Binaphthalene]-2,2’-diylbis[diphenylphosphine]-P,P’]chloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene]ruthenium(1+) Chloride; (S)-[1,1’-Binaphthalene]-2,2’-diylbis[diphenylphosphine Ruthenium Complex; ((S)-(2,2’-Bis(diphenylphosphino)-1,1’-binaphthyl))(chloro)(η6-p-isopropyltoluene)ruthenium(1+) Chloride; ((S)-2,2’-Bis(diphenylphosphino)-1,1’-binaphthyl)(chloro)(η6-4-isopropyltoluene)ruthenium(1+) Chloride; [(1S)-[1,1’-Binaphthalene]-2,2’-diylbis[diphenylphosphine-κP]]chloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene]ruthenium(1+) Chloride
CAS Number: 130004-33-0
Possible CAS #: NA
Molecular form.: C₅₄H₄₆Cl₂P₂Ru
Appearance: Brownish Yellow Solid
Melting Point: >160°C (dec.)
Mol. Weight: 928.87
Storage: Hygroscopic, Refrigerator, under inert atmosphere
Solubility: Chloroform (Sparingly)
Stability: No Data Available
Category: Aromatics, Catalyst, Miscellaneous Reagents
Boiling Point: No Data Available
Applications: [2,2’-Bis(diphenylphosphino)-1,1’-binaphthalene]chloro(p-cymene)ruthenium Chloride is used as a catalyst in the asymmetric synthesis of UK 370106 (U700620); an MMP-3 inhibitor. It is also highly effective in the hydrogenation of 2-(6’-methoxy-2’-naphthyl)propenoic acid and β-ketoesters.
Dangerous Goods Info: NA
References:
Peer Review Product Citations:

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